发表于2024-12-23
Contents
1 Bonding and Isomerism(键合和异构)
1.1 How Electrons Are Arranged in Atoms(原子中的电子排布)
1.2 Ionic and Covalent Bonding(离子键和共价键)
1.3 Carbon and the Covalent Bond(碳原子和共价键)
1.4 Carbon-Carbon Single Bonds(碳-碳单键)
1.5 Polar Covalent Bonds(极性共价键)
1.6 Multiple Covalent Bonds(多重共价键)
1.7 Valence(化合价)
1.8 Isomerism(异构现象)
1.9 Writing Structural Formulas(结构式的书写)
1.10 Abbreviated Structural Formulas(简化结构式)
1.11 Formal Charge(形式电荷)
1.12 Resonance(共振理论)
1.13 Arrow Formalism(箭头形式)
1.14 The Orbital View of Bonding; the Sigma Bond(共价键的轨道理论;σ键)
1.15 Carbon sp3 Hybrid Orbitals(碳的sp3杂化轨道)
1.16 Tetrahedral Carbon; the Bonding in Methane(碳原子的四面体结构;甲烷分子中的碳氢键)
1.17 Classification According to Molecular Framework(按分子骨架分类)
1.18 Classification According to Functional Group(按功能基分类)
2 Alkanes and Cycloalkanes; Conformational and Geometric Isomerism(烷烃和环烷烃;构象和几何异构)
2.1 The Structures of Alkanes(烷烃的结构)
2.2 Nomenclature of Organic Compounds(有机化合物的命名)
2.3 IUPAC Rules for Naming Alkanes(烷烃的IUPAC命名规则)
2.4 Alkyl and Halogen Substituents(烷基和卤素取代基)
2.5 Use of the IUPAC Rules(IUPAC命名规则的应用)
2.6 Sources of Alkanes(烷烃的来源)
2.7 Physical Properties of Alkanes and Nonbonding Intermolecular Interactions(烷烃的物理性质和分子间的非键作用)
2.8 Conformations of Alkanes(烷烃的构象)
2.9 Cycloalkane Nomenclature and Conformation(环烷烃的命名和构象)
2.10 Cis-Trans Isomerism in Cycloalkanes(环烷烃的顺反异构)
2.11 Summary of Isomerism(异构现象小结)
2.12 Reactions of Alkanes(烷烃的化学反应)
2.13 The Free-Radical Chain Mechanism of Halogenation(烷烃卤代的自由基链反应机制)
3 Alkenes and Alkynes(烯烃和炔烃)
3.1 Definition and Classification(定义和分类)
3.2 Nomenclature(命名)
3.3 Some Facts about Double Bonds(碳碳双键的特征)
3.4 The Orbital Model of a Double Bond; the Pi Bond(碳碳双键的轨道模型;π键)
3.5 Cis-Trans Isomerism in Alkenes(烯烃的顺反异构现象)
3.6 Addition and Substitution Reactions Compared(加成和取代反应的比较)
3.7 Polar Addition Reactions(极性加成反应)
3.8 Addition of Unsymmetric Reagents to Unsymmetric Alkenes; Markovnikov‘s Rule(不对称试剂与不对称烯烃的加成;马尔可夫尼可夫规则)
3.9 Mechanism of Electrophilic Addition to Alkenes(烯烃的亲电加成机制)
3.10 Markovnikov’s Rule Explained(马尔可夫尼可夫规则的解释)
3.11 Reaction Equilibrium: What Makes a Reaction Go?(反应平衡:什么使反应能够进行下去?)
3.12 Reaction Rates: How Fast Does a Reaction Go?(反应速率:反应进行得有多快?)
3.13 Hydroboration of Alkenes(烯烃的硼氢化反应)
3.14 Addition of Hydrogen(加氢反应)
3.15 Additions to Conjugated Systems(共轭烯烃的加成反应)
3.16 Free-Radical Additions; Polyethylene(自由基加成反应;聚乙烯)
3.17 Oxidation of Alkenes(烯烃的氧化)
3.18 Some Facts about Triple Bonds(叁键的特征)
3.19 The Orbital Model of a Triple Bond(叁键的轨道模型)
3.20 Addition Reactions of Alkynes(炔烃的加成反应)
3.21 Acidity of Alkynes(炔烃的酸性)
4 Aromatic Compounds(芳香化合物)
4.1 Some Facts about Benzene(有关苯的实验事实)
4.2 The Kekulé Structure of Benzene(苯的凯库勒结构式)
4.3 Resonance Model for Benzene(苯的共振结构模型)
4.4 Orbital Model for Benzene(苯的轨道模型)
4.5 Symbols for Benzene(苯的结构表达式)
4.6 Nomenclature of Aromatic Compounds(芳香族化合物的命名)
4.7 The Resonance Energy of Benzene(苯的共振能)
4.8 Electrophilic Aromatic Substitution(芳香亲电取代反应)
4.9 The Mechanism of Electrophilic Aromatic Substitution(芳香亲电取代反应的机制)
4.10 Ring-Activating and Ring-Deactivating Substituents(苯环的活化基和钝化基)
4.11 Ortho,Para-Directing and Meta-Directing Groups(邻,对位定位基和间位定位基)
4.12 The Importance of Directing Effects in Synthesis(定位效应在合成中的重要性)
4.13 Polycyclic Aromatic Hydrocarbons(多环芳香烃)
5 Stereoisomerism(立体异构)
5.1 Chirality and Enantiomers(手性和对映异构体)
5.2 Stereogenic Centers; the Stereogenic Carbon Atom(手性中心;手性碳原子)
5.3 Configuration and the R-S Convention(R-S 构型)
5.4 Polarized Light and Optical Activity(偏振光和光学活性)
5.5 Properties of Enantiomers(对映异构体的性质)
5.6 Fischer Projection Formulas(费歇尔投影式)
5.7 Compounds with More Than One Stereogenic Center; Diastereomers(具有多个手性中心的化合物;非对映异构体)
5.8 Meso Compounds; the Stereoisomers of Tartaric Acid(内消旋化合物;酒石酸的立体异构体)
5.9 Stereochemistry: A Recap of Definitions(立体化学:定义概述)
5.10 Stereochemistry and Chemical Reactions(立体化学和化学反应)
5.11 Resolution of a Racemic Mixture(外消旋体的拆分)
6 Organic Halogen Compounds; Substitution and Elimination Reactions(含卤有机化合物;取代反应和消除反应)
6.1 Nucleophilic Substitution(亲核取代反应)
6.2 Examples of Nucleophilic Substitutions(亲核取代反应实例)
6.3 Nucleophilic Substitution Mechanisms(亲核取代反应机制)
6.4 The SN2 Mechanism(双分子亲核取代机制)
6.5 The SN1 Mechanism(单分子亲核取代机制)
6.6 The SN1 and SN2 Mechanisms Compared(SN1和SN2反应机制的比较)
6.7 Dehydrohalogenation, an Elimination Reaction; the E2 and E1 Mechanisms(脱卤化氢,消除反应;双分子消除和单分子消除机制)
6.8 Substitution and Elimination in Competition(取代反应和消除反应的相互竞争)
6.9 Polyhalogenated Aliphatic Compounds(多卤代脂肪烃)
7 Alcohols, Phenols, and Thiols(醇,酚和硫醇)
7.1 Nomenclature of Alcohols(醇的命名)
7.2 Classification of Alcohols(醇的分类)
7.3 Nomenclature of Phenols(酚的命名)
7.4 Hydrogen Bonding in Alcohols and Phenols(醇和酚分子中的氢键)
7.5 Acidity and Basicity Reviewed(酸性和碱性)
7.6 The Acidity of Alcohols and Phenols(醇和酚的酸性)
7.7 The Basicity of Alcohols and Phenols(醇和酚的碱性)
7.8 Dehydration of Alcohols to Alkenes(醇脱水生成烯烃的反应)
7.9 The Reaction of Alcohols with Hydrogen Halides(醇与卤化氢的反应)
7.10 Other Ways to Prepare Alkyl Halides from Alcohols(由醇制备卤代烃的方法)
7.11 A Comparison of Alcohols and Phenols(醇和酚的比较)
7.12 Oxidation of Alcohols to Aldehydes, Ketones, and Carboxylic Acids(醇的氧化反应--生成醛,酮和羧酸)
7.13 Alcohols with More Than One Hydroxyl Group(多元醇)
7.14 Aromatic Substitution in Phenols(酚的芳香取代反应)
7.15 Oxidation of Phenols(酚的氧化反应)
7.16 Phenols as Antioxidants(酚类抗氧化剂)
7.17 Tests for Phenols(酚的鉴别)
7.18 Thiols, the Sulfur Analogs of Alcohols and Phenols(硫醇,醇和酚的硫类似物)
8 Ethers and Epoxides(醚和环氧化合物)
8.1 Nomenclature of Ethers(醚的命名)
8.2 Physical Properties of Ethers(醚的物理性质)
8.3 Ethers as Solvents(醚作溶剂)
8.4 The Grignard Reagent; an Organometallic Compound(格利雅试剂;一种有机金属化合物)
8.5 Preparation of Ethers(醚的制备)
8.6 Cleavage of Ethers(醚的裂解)
8.7 Epoxides (Oxiranes)[环氧化物(环氧乙烷)]
8.8 Reactions of Epoxides(环氧化物的反应)
8.9 Cyclic Ethers(环醚)
9 Aldehydes and Ketones(醛和酮)
9.1 Nomenclature of Aldehydes and Ketones(醛和酮的命名)
9.2 Some Common Aldehydes and Ketones(常见的醛和酮)
9.3 Synthesis of Aldehydes and Ketones(醛和酮的制备)
9.4 Aldehydes and Ketones in Nature(天然醛酮)
9.5 The Carbonyl Group(羰基)
9.6 Nucleophilic Addition to Carbonyl Groups: An Overview(羰基的亲核加成:概述)
9.7 Addition of Alcohols: Formation of Hemiacetals and Acetals(与醇加成:生成半缩醛和缩醛)
9.8 Addition of Water; Hydration of Aldehydes and Ketones(与水加成:醛酮的水合)
9.9 Addition of Grignard Reagents and Acetylides(与Grignard试剂和炔化物加成)
9.10 Addition of Hydrogen Cyanide; Cyanohydrins(与氢氰酸加成:生成氰醇)
9.11 Addition of Nitrogen Nucleophiles(与含氮亲核试剂加成)
9.12 Reduction of Carbonyl Compounds(羰基化合物的还原)
9.13 Oxidation of Carbonyl Compounds(羰基化合物的氧化)
9.14 Keto-Enol Tautomerism(酮式-烯醇式互变异构)
9.15 Acidity of a-Hydrogens; the Enolate Anion(a-氢的酸性;烯醇负离子)
9.16 Deuterium Exchange in Carbonyl Compounds(羰基化合物的氘代)
9.17 Halogenation(卤代反应)
9.18 The Aldol Condensation(醇醛缩合反应)
9.19 The Mixed Aldol Condensation(混合醇醛缩合)
9.20 Commercial Syntheses via the Aldol Condensation(醇醛缩合反应在合成中的应用)
10 Carboxylic Acids and Their Derivatives(羧酸及其衍生物)
10.1 Nomenclature of Acids(羧酸的命名)
10.2 Physical Properties of Acids(羧酸的物理性质)
10.3 Acidity and Acidity Constants(酸性和酸度常数)
10.4 What Makes Carboxylic Acids Acidic?(羧酸的酸性基)
10.5 Effect of Structure on Acidity; the Inductive Effect Revisited(羧酸的结构对酸性的影响;诱导效应的影响)
10.6 Conversion of Acids to Salts(成盐反应)
10.7 Preparation of Acids(羧酸的制备)
10.8 Decarboxylation(脱羧反应)
10.9 Carboxylic Acid Derivatives(羧酸衍生物)
10.10 Esters(酯)
10.11 Preparation of Esters; Fischer Esterification(酯的制备;Fischer酯化反应)
10.12 The Mechanism of Acid-Catalyzed Esterification; Nucleophilic Acyl Substitution(酸催化酯化反应机制;酰基的亲核取代)
10.13 Lactones(内酯)
10.14 Saponification of Esters(酯的皂化反应)
10.15 Ammonolysis of Esters(酯的氨解)
10.16 Reaction of Esters with Grignard Reagents(酯与格利雅试剂的反应)
10.17 Reduction of Esters(酯的还原)
10.18 The Need for Activated Acyl Co
国外名校名著:有机化学(原著第13版) 下载 mobi epub pdf txt 电子书 格式
国外名校名著:有机化学(原著第13版) 下载 mobi pdf epub txt 电子书 格式 2024
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