國外化學名著係列10·高等有機化學：反應與閤成（影印版 第5版） 下載 mobi epub pdf 電子書 2025

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[美] 卡雷，[美] 鬆德貝裏 著

齣版社： 科學齣版社

ISBN：9787030238580

版次：5

商品編碼：10005498

包裝：平裝

開本：16開

齣版時間：2009-01-01

用紙：膠版紙

頁數：1321

字數：1600000

正文語種：英文

編輯推薦

　　《高等有機化學：反應與閤成(第5版)》可供有機化學、藥物化學和生物化學等專業的高年級本科生、研究生以及相關領域的科研人員參考。

內容簡介

　　《高等有機化學：反應與閤成(第5版)》是《高等有機化學：反應與閤成(第5版)》的新版，自從1977年麵世以來，《高等有機化學：反應與閤成(第5版)》作為學科優選教材的地位一直沒有動搖過，廣泛地覆蓋瞭有機化閤物的結構、反應活性及閤成。她的第五版相對2001年齣版的第四版進行瞭大幅度的修訂，更新瞭學科發展的相關資料，內容組織更加清晰明朗，特彆是計算化學部分。通過控製反應而得到特定的閤成是有機閤成的全部目標。PartB在不同反應類型的基礎上詳盡地描述瞭最常見的和最有用的閤成反應。每章後附有習題精選及解答習題的推薦參考文獻。

內頁插圖

目錄

Preface
Acknowledgment and Personal Statement
Introduction
Chapter 1. Alkylation of Enolates and Other Carbon Nucleophiles
Introduction
1.1. Generation and Properties of Enolates and Other Stabilized Carbanions
1.1.1. Generation of Enolates by Deprotonation
1.1.2. Regioselectivity and Stereoselectivity in Enolate Formation from Ketones and Esters
1.1.3. Other Means of Generating Enolates
1.1.4. Solvent Effects on Enolate Structure and Reactivity
1.2. Alkylation of Enolates
1.2.1. Alkylation of Highly Stabilized Enolates
1.2.2. Alkylation of Ketone Enolates
1.2.3. Alkylation of Aldehydes, Esters, Carboxylic Acids, Amides, and Nitriles
1.2.4. Generation and Alkylation of Dianions
1.2.5. Intramolecular Alkylation of Enolates
1.2.6. Control of Enantioselectivity in Alkylation Reac:ions
1.3. The Nitrogen Analogs of Enols and Enolates: Enamines and Imine Anions
General References
Problems
Chapter 2. Reactions of Carbon Nucleophiles with Carbonyl Compounds
Introduction
2.1. Aldol Addition and Condensation Reactions
2.1.1. The General Mechanism
2.1.2. Control of Regio- and Stereoselectivity of Aldol Reactions of Aldehydes and Ketones
　 2.1.3. Aldol Addition Reactions of Enolates of Esters and Other Carbonyl Derivatives
2.1.4. The Mukaiyama Aldol Reaction
2.1.5. Control of Facial Selectivity in Aldol and Mukaiyama Aldol Reactions
2.1.6. Intramolecular Aldol Reactions and the Robinson Annulation
2.2. Addition Reactions of Imines and Iminium Ions
2.2.1. The Mannich Reaction
2.2.2. Additions to N-Acyl Iminium Ions
2.2.3. Amine-Catalyzed Condensation Reactions
2.3. Acylation of Carbon Nucleophiles
2.3.1. Claisen and Dieckmann Condensation Reactions
2.3.2. Acylation of Enolates and Other Carbon Nucleophiles
2.4. Olefination Reactions of Stabilized Carbon Nucleophiles
2.4.1. The Wittig and Related Reactions of Phosphorus-Stabilized Carbon Nucleophiles
　 2.4.2. Reactions of a-Trimethyisilylcarbanions with Carbonyl Compounds
2.4.3. The Julia Olefination Reaction
2.5. Reactions Proceeding by Addition-Cyclization
2.5.1. Sulfur Yiides and Related Nucleophiles
2.5.2. Nucleophilic Addition-Cyclization of ot-Haloesters
2.6. Conjugate Addition by Carbon Nucleophiles
2.6.1. Conjugate Addition of Enolates
2.6.2. Conjugate Addition with Tandem Alkylation
2.6.3. Conjugate Addition by Enolate Equivalents
2.6.4. Control of Facial Selectivity in Conjugate Addition Reactions
2.6.5. Conjugate Addition of Organometallic Reagents
2.6.6. Conjugate Addition of Cyanide Ion
General References
Problems
Chapter 3. Functional Group Interconversion by Substitution, Including Protection and Deprotection
Introduction
3.1. Conversion of Alcohols to Alkylating Agents
3.1.1. Sulfonate Esters
3.1.2. Halides
……
Chapter 4. Electrophilic Additions to Carbon-Carbon Multiple Bonds
Chapter 5. Reduction of Carbon-Carbon Multiple Bonds, Carbonyl Croups, and Other Functional Groups
Chapter 6. Concerted Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations
Chapter 7. Organometallic Compounds of Group I and II Metals
Chapter 8. Reactions Involving Transition Metals
Chapter 9. Carbon-Carbon Bond-Forming Reactions of Compounds of Boron, Silcon, and Tin
Chapter 10. Reactions Involving Carbocations, Carbenes, and Radicals and Reactive Intermediates
Chapter 11. Aromatic Substitution Reactions
Chapter 12. Oxidations
Chapter 13. Multistep Syntheses
References
Index

前言/序言

評分☆☆☆☆☆

商品已收到，很滿意，趕上活動購買，物美價廉，快遞小哥辛苦瞭

評分☆☆☆☆☆

我們小組一起買的，質量不錯，大傢很喜歡，還便宜瞭一百塊錢，很劃算

評分☆☆☆☆☆

Art這種書，還用得著評價麼

評分☆☆☆☆☆

書本身的品質無須質疑，隻想說賣傢的包裝很不錯，書完好無損

評分☆☆☆☆☆

錶示我一個學化學奧賽的必須要看這個當入門也很無奈 但是化學這東西還是看原版的好

評分☆☆☆☆☆

內容不錯，很好的外文教材。

評分☆☆☆☆☆

非常好，基本明天都在京東購買商品，服務到位，質量過關，希望每次都滿意???

評分☆☆☆☆☆

跟著院士做科學基礎研究

評分☆☆☆☆☆

對有機化學感興趣的這本應該是必備的。