內容簡介
Preface
This book has been written to fill a gap in the literature by offering a standard and overall coverage of colloid and surface chemistry intermediate between the brief accounts found in most textbooks of physical chemistry and the comprehensive accounts found in specialized treaties on colloid and/or surface chemistry.
In writing the book, I have kept a number of audiences in mind-particularly: university and polytechnic students studying for an honours degree or its equivalent, or commencing a programme of postgraduate research; scientists in industry who desire a broad background in a subject which may have been somewhat neglected during academic training; and those interested in branches of natural science, for whom an understanding of colloid and surface phenomena is essential.
The subject matter is, in general, approached from a fundamental angle, and the reader is assumed to possess a knowledge of the basic principles of physical chemistry. Opportunities have also been taken to describe many of the practical applications of this subject. In addition, some numerical problems (with answers) and a list of references for further reading (mainly books and review articles) are given at the end of the book.
The general character os this fourth edidion is similar to that of the third edition. The text has been revised and updated throughout, the major change being the extension of Chapter 5 to include a section on the composition and structure of solid surfaces.
I wish to thank my colleagues, particularly Dr A.L.Smith, for their many helpful suggestions, and my wife, Ann, for her help in preparing the manuscipt and checking the text.
D.J.S
目錄
Preface.
1 The colloidal state
Introduction
Classification of colloidal systems
Structural characteristics
Preparation and purification of colloidal systems
2 Kinetic properties
The motion of particles in liquid media
Brownian motion and translational diffusion
The ultracentrifuge
Osmotic pressure
Rotary Brownian motion
3 Optical properties
Optical and electron microscopy
Light scattering
4 Liquid-gas and liquid-liquid interfaces
Surface and interfacial tensions
Adsorption and orientation at interfaces
Association colloids-micelle formation
Spreading
Monomolecular films
5 The solid-gas interface
Adsorption of gases and vapours on solids
Compsition and structure of solid surfaces
6 The solid-liquid interface
Contact angles and wetting
Ore flotation
Detergency
Adsorption from solution
7 Charged interfaces
The electric double layer
Electrokinetic phenomena
Electrokinetic theory
8 Colloid stability
Lyophobic sols
Systems containing lyophilic material
Stability control
9 Rheology
Introduction
Viscosity
Non-Newtonian flow
Viscoelasticity
10 Emulsions and foams
Oil-in-water and water-in-oil emulsions
Foams
Problems
Answers
References
Index
前言/序言
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